化学所分子识别与功能实验室
学术带头人

        王其强  研究员

        

        电话:86-10-69943703

        传真:86-10-62564723

        邮箱:qiqiangw@iccas.ac.cn

        课题组主页:http://supramolchemcat.iccas.ac.cn

     

    学术经历

    1999-2003   武汉大学学士学位

    2003-2008   中国科学院化学研究所博士学位

    2008-2013   美国堪萨斯大学博士后

    2014-2015   荷兰阿姆斯特丹大学博士后

    2015-至今   中国科学院化学研究所,研究员  

     

    荣誉与奖项

    2007   中国科学院化学研究所青年科学特别奖

    2006   中国科学院化学研究所青年科学优秀奖

    2005   中国科学院化学研究所青年科学优秀奖

     

    研究方向

    建立物质转化的高效催化体系对可持续化学、绿色化学和能源化学的发展具有重大意义。超分子化学的发展能为高效催化体系的构筑提供丰富的非共价键工具与组装手段,为设计与开发新催化剂、探索新催化反应、开辟物质转化新途径提供了重要思路。我们围绕超分子化学与催化的前沿交叉领域,开展“超分子催化”研究。致力于构建新型的大环超分子催化体系,运用各种超分子手段如自组装高效便捷地构建催化剂库;进行理性的超分子设计构筑功能化的微环境实现高催化活性与特殊反应性;控制催化剂和反应组分间的特定作用方式提高催化的选择性如化学、立体及对映选择性。具体研究方向包括:

    1. 超分子催化

    2. 大环超分子化学

    3. 分子识别与组装

     

    Selected Work

    1. Molecular barrel by a hooping Strategy: Synthesis, structure, and selective CO2 adsorption facilitated by lone pair−π interactions

    J. Am. Chem. Soc. 2017139, 635-638.

     

    2. Self-assembled nanospheres with multiple endohedral binding sites pre-organize catalysts and substrates for highly efficient reactions

    Nature Chem. 2016, 8, 225-230. (Postdoc work at University of Amsterdam with Prof. Joost N. H. Reek)

     

    3. Anion coordination chemistry: A unique tetrahedron host as “water box” for tetrahedral clusters in solid state and for naked fluoride in solution

    Angew. Chem. Int. Ed. 2012, 51, 2119; J. Am. Chem. Soc. 2013, 135, 392.(Postdoc work at University of Kansas with Prof. Kristin Bowman-James)

     

    Selected Publications

    1. Wang, Q.-Q.*; Luo, N.; Wang, X.-D.; Ao, Y.-F.; Chen, Y-F; Liu J.-M.*; Su, C.-Y.; Wang, D.-X.; Wang, M.-X.* “Molecular barrel by a hooping strategy: Synthesis, structure, and selective CO2 adsorption facilitated by lone pair−π interactions” J. Am. Chem. Soc. 2017139, 635-638.

    2. Xu, R.-B.; Wang, Q.-Q.*; Ao, Y.-F.; Li, Z.-Y.; Huang, Z.-T.; Wang, D.-X.* “Anionic head containing oxacalix[2]arene[2]triazines: Synthesis and anion−π-directed self-assembly in solution and solid state” Org. Lett. 201719, 738-741.

    3. Wang, Q.-Q.; Gonell, S.; Leenders, S. H. A. M.; Dürr, M.; Ivanović-Burmazović, I.; Reek, J. N. H.* “Self-assembled nanospheres with multiple endohedral binding sites pre-organize catalysts and substrates for highly efficient reactions” Nature Chem. 2016, 8, 225-230.

    4. Wang, Q.-Q.; Day, V. W.; Bowman-James, K.* “Macrocyclic influences in CO2 uptake and stabilization” Org. Lett. 2014, 16, 3982-3985.

    5. Wang, Q.-Q.; Begum, R. A.; Day, V. W.; Bowman-James, K.* “Chemical mustard containment using simple palladium pincer complexes: The influence of molecular walls” J. Am. Chem. Soc. 2013, 135, 17193-17199.

    6. Wang, Q.-Q.; Day, V. W.; Bowman-James, K.* “Chemistry and structure of a host-guest relationship: The power of NMR and X-ray diffraction in tandem” J. Am. Chem. Soc. 2013, 135, 392-399.

    7. Wang, Q.-Q.; Day, V. W.; Bowman-James, K.* “Hexagonal molecular “palladawheel”” Chem. Commun. 2013, 49, 8042-8044.

    8. Wang, Q.-Q.; Day, V. W.; Bowman-James, K.* “Supramolecular encapsulation of tetrahedrally hydrated guests in a tetrahedron host” Angew. Chem. Int. Ed. 2012, 51, 2119-2123. (Covered on the book “Anion Coordination Chemistry”, Bowman-James, K.; Bianchi, A.; García-España E. Eds. Wiley-VCH: 2012)

    9. Wang, Q.-Q.; Begum, R. A.; Day, V. W.; Bowman-James, K.* “Molecular thioamide ↔ iminothiolate switches for sulfur mustards” Inorg. Chem. 2012, 51, 760-762.

    10. Wang, Q.-Q.; Begum, R. A.; Day, V. W.; Bowman-James, K.* “Sulfur, oxygen, and nitrogen mustards: Stability and reactivity” Org. Biomol. Chem. 2012, 10, 8786-8793. (Inside front cover)

    11. Wang, Q.-Q.; Day, V. W.; Bowman-James, K.* “Tunable, shape-shifting capsule for dicarboxylates” Chem. Sci. 2011, 2, 1735-1738. (Top ten most accessed articles in July, 2011)

    12. Wang, Q.-Q.; Wang, D.-X.*; Yang, H.-B.; Huang, Z.-T.; Wang, M.-X.* “Synthesis, structure and molecular recognition of functionalised tetraoxacalix[2]arene[2]triazines” Chem. Eur. J. 2010, 16, 7265-7275.

    13. Wang, Q.-Q.; Wang, D.-X.; Zheng, Q.-Y.; Wang, M.-X.* “Formation and conformational conversion of flattened partial cone oxygen-bridged calix[2]arene[2]triazines” Org. Lett. 2007, 9, 2847-2850.

    14. Wang, Q.-Q.; Wang, D.-X.; Ma, H.-W.; Wang, M.-X.* “Synthesis of tetraazacalix[2] arene[2]triazines: Tuning the cavity by the substituents on the bridging nitrogen atoms” Org. Lett. 2006, 8, 5967-5970.

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